Epoxy curing agent Knowledge Salicyl alcohol

Salicyl alcohol

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Salicyl alcohol structural formula

Structural formula

Business number 021S
Molecular formula C7H8O2
Molecular weight 124.14
label

o-hydroxybenzyl alcohol,

2-Hydroxybenzyl alcohol,

o-hydroxybenzyl alcohol,

2-hydroxybenzyl alcohol,

2-Hydroxybenzyl alcohol,

Saligenin,

o-Hydroxybenzyl alcohol,

HOC6H4CH2OH

Numbering system

CAS number:90-01-7

MDL number:MFCD00004617

EINECS number:201-960-5

RTECS number:DO6430000

BRN number:1907195

PubChem number:24850189

Physical property data

1. Properties: white flake or crystalline powder. Spicy.

2. Density (g/mL, 25/4℃): 1.16

3. Relative vapor density (g/mL, air=1): Undetermined

4. Melting point (ºC): 86~87

5. Boiling point (ºC, normal pressure): Undetermined

6. Boiling point (ºC, 5.2kPa): Undetermined Determined

7. Refractive index: Undetermined

8. Flash point (ºC): Undetermined

9. Specific rotation (º): Undetermined

10. Autoignition point or ignition temperature (ºC): Undetermined

11. Vapor pressure (kPa, 25ºC): Undetermined

12. Saturation Vapor pressure (kPa, 60ºC): Undetermined

13. Heat of combustion (KJ/mol): Undetermined

14. Critical temperature (ºC): Undetermined

15. Critical pressure (KPa): Undetermined

16. Log value of oil-water (octanol/water) partition coefficient: Undetermined

17. Explosion upper limit (% , V/V): Undetermined

18. Lower explosion limit (%, V/V): Undetermined

19. Solubility: Easily soluble in ethanol, ether and chloroform, Soluble in benzene and 15 parts of water. It turns red when encountering sulfuric acid.

Toxicological data

irritating

Ecological data

None

Molecular structure data

1. Molar refractive index 34.58

2. Molar volume (cm3/mol): 101.6

3. Isotonic specific volume (90.2K) :275.8

4. Surface tension (dyne/cm): 54.1

5��� Polarizability (10-24cm3): 13.71

Compute chemical data

1. Hydrophobic parameter calculation reference value (XlogP): 0.7

2. Number of hydrogen bond donors: 2

3. Number of hydrogen bond acceptors: 2

4. Number of rotatable chemical bonds: 1

5. Number of tautomers: 3

6. Topological molecular polar surface area (TPSA): 40.5

p>

7. Number of heavy atoms: 9

8. Surface charge: 0

9. Complexity: 83

10. Number of isotope atoms : 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the chemical bond configuration Number of centers: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 1

Properties and stability

None

Storage method

This product should be kept sealed.

Synthesis method

1. Add zinc acetate to a mixture of phenol and formaldehyde solution, adjust the pH to 5-6, slowly heat and reflux for 1 hour, vacuum distill to remove water and excess phenol, and the temperature does not exceed 100°C. The residue in the kettle is stirred evenly with carbon tetrachloride and then left to stand. The precipitated salicyl alcohol is crystallized again with carbon tetrachloride to obtain the finished product.

2. Preparation method:

Add 1.5 mL of 2 mol/L ferrous chloride aqueous solution, 0.5 g of platinum oxide, 73.2 g (0.6 mol) of salicylaldehyde (2), and 300 mL of 95% ethanol into the high-pressure reaction kettle. Replace the air with nitrogen, and then replace the nitrogen with hydrogen. Stir at room temperature under a pressure of 0.3MPa until hydrogen is no longer absorbed, which takes about 1 to 2 hours. Release the residual pressure and open the reactor. Add 1 to 2 mL of 1 mol/L sodium hydroxide solution, filter to recover the catalyst, and wash with 20 mL (95%) ethanol. Combine the filtrate and washing liquid, rotate and concentrate, and the residue is recrystallized with 150 mL benzene to obtain product (1) 67.9, with a yield of 92%. Note: ① This method can be used to prepare the following benzyl alcohols (Table I-5-7) [1]

Purpose

It is used to make coumarin and prepare spices such as violet. It is also used to synthesize the pesticide salicylthion and medicine.

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