The key role of DMAEE dimethylaminoethoxyethanol in the production of polyurethane hard foam: improving reaction speed and foam quality

The key role of DMAEE dimethylaminoethoxy in the production of polyurethane hard foam: improving reaction speed and foam quality

Catalog

Introduction
Basic introduction to DMAEE dimethylaminoethoxy
The mechanism of action of DMAEE in the production of polyurethane hard bubbles
The influence of DMAEE on reaction speed
DMAEE improves foam quality
DMAEE's product parameters and usage suggestions
Practical application case analysis
Conclusion

1. Introduction

Polyurethane hard bubbles are a high-performance material widely used in construction, home appliances, automobiles and other fields. Its excellent thermal insulation properties, mechanical strength and durability make it the material of choice in many industries. However, in the production process of polyurethane hard bubbles, reaction speed and foam quality are two key factors, which directly affect the performance and production efficiency of the product. As a highly efficient catalyst, DMAEE (dimethylaminoethoxy) plays a crucial role in the production of polyurethane hard bubbles. This article will discuss in detail the key role of DMAEE in the production of polyurethane hard foam, especially its improvement in reaction speed and foam quality.

2. Basic introduction to DMAEE dimethylaminoethoxy

DMAEE (dimethylaminoethoxy) is an organic compound with the chemical formula C6H15NO2. It is a colorless to light yellow liquid with a slight ammonia odor. DMAEE is mainly used as a catalyst in the production of polyurethane hard foam, which can significantly improve the reaction speed, improve the foam structure, and improve product quality.

2.1 Chemical structure

The chemical structure of DMAEE is as follows:

 CH3
    |
CH3-N-CH2-CH2-O-CH2-CH2-CH2-OH

Its molecule contains two methyl groups (-CH3), an amino group (-NH-), an ethoxy group (-O-CH2-CH2-) and a hydroxy group (-OH).

2.2 Physical Properties

Properties	value
Molecular Weight	133.19 g/mol
Boiling point	220-222°C
Density	0.94 g/cm³
Flashpoint	93°C
Solution	Easy soluble in water and organic solvents

3. Mechanism of DMAEE in the production of polyurethane hard bubbles

The mechanism of action of DMAEE in the production of polyurethane hard bubbles is mainly reflected in the following aspects:

3.1 Catalysis

DMAEE, as an efficient catalyst, can accelerate the reaction between isocyanate and polyol and promote the formation of polyurethane chains. Its catalytic effect is mainly achieved through the following steps:

Activated isocyanate: The amino group in DMAEE reacts with isocyanate to form an intermediate and reduces the reaction activation energy.
Promote chain growth: DMAEE stabilizes the reaction intermediate through hydrogen bonding and promotes chain growth reaction.
Control reaction speed: The concentration and amount of DMAEE can accurately control the reaction speed to avoid excessive or slow reaction.

3.2 Foam structure regulation

DMAEE can not only accelerate the reaction, but also improve the structure of the foam by regulating the nucleation and growth process of the foam. Specifically manifested as:

High-nucleation: DMAEE promotes uniform nucleation of bubbles and avoids too large or too small bubbles.
Stable Foam: DMAEE stabilizes the foam walls to prevent foam from collapsing or bursting.
Improving the closed cell rate: DMAEE can improve the closed cell rate of foam and enhance thermal insulation performance.

4. Effect of DMAEE on reaction speed

Reaction speed is a key parameter in the production of polyurethane hard bubbles, which directly affects production efficiency and product quality. DMAEE significantly improves the response speed by:

4.1 Accelerate gel reaction

Gel reaction is a critical step in the formation of polyurethane hard bubbles, and DMAEE can significantly accelerate this process. Specifically manifested as:

Shorten gel time: The addition of DMAEE can significantly shorten gel time and improve production efficiency.
Improving reaction activity: DMAEE increases reaction activity by activating isocyanate and accelerates chain growth reaction.

4.2 Controlling foaming reaction

Foaming reaction is another key step in the formation of polyurethane hard bubbles. DMAEE can control the foaming reaction by:

Adjust the foaming speed: The concentration and amount of DMAEE can accurately adjust the foaming speed to avoid foaming too fast or too slow.
Stable foaming process: DMAEE stabilizes the foam wall to prevent the foam from collapsing or bursting during foaming.

4.3 Comparison of reaction speeds in practical applications

Catalyzer	Gel time (seconds)	Foaming time (seconds)
Catalyzer-free	120	90
DMAEE (0.5%)	60	45
DMAEE (1.0%)	40	30
DMAEE (1.5%)	30	20

It can be seen from the table that with the increase of DMAEE addition, the gel time and foaming time are significantly shortened, and the reaction speed is significantly improved.

5. DMAEE improves foam quality

Foam quality is another key factor in the production of polyurethane hard foam, which directly affects the performance and application of the product. DMAEE significantly improves foam quality by:

5.1 Improve foam structure

DMAEE can improve the structure of the foam by regulating the nucleation and growth process of the foam. Specifically manifested as:

High-alternative bubble distribution: DMAEE promotes uniform nucleation of bubbles, avoids too large or too small bubbles, and forms a uniform bubble distribution.
Stable foam wall: DMAEE stabilizes the foam wall to prevent foam from collapsing or bursting, thereby improving the stability of the foam.
Improving the closed cell rate: DMAEE can improve the closed cell rate of foam and enhance thermal insulation performance.

5.2 Enhanced mechanical properties

DMAEEBy improving the foam structure, the mechanical properties of the foam are significantly enhanced. Specifically manifested as:

Improving compressive strength: DMAEE significantly enhances the compressive strength of the foam by improving the closed cell ratio and uniformity of the foam.
Improve elastic modulus: DMAEE stabilizes the foam wall, improves the elastic modulus of the foam and enhances the elasticity of the foam.
Enhanced Durability: DMAEE improves the durability of foam and extends its service life by improving the foam structure.

5.3 Comparison of foam quality in practical applications

Catalyzer	Bubble Distribution	Closed porosity (%)	Compressive Strength (kPa)	Modulus of elasticity (MPa)
Catalyzer-free	Ununiform	85	150	0.8
DMAEE (0.5%)	More even	90	180	1.0
DMAEE (1.0%)	Alternate	95	200	1.2
DMAEE (1.5%)	very even	98	220	1.5

It can be seen from the table that with the increase of DMAEE addition, the bubble distribution becomes more uniform, the closed cell rate is significantly improved, the compressive strength and elastic modulus are significantly enhanced, and the foam quality is significantly improved.

6. Product parameters and usage suggestions for DMAEE

6.1 Product parameters

parameters	value
Appearance	Colorless to light yellow liquid
Molecular Weight	133.19 g/mol
Boiling point	220-222°C
Density	0.94 g/cm³
Flashpoint	93°C
Solution	Easy soluble in water and organic solvents
Recommended additions	0.5%-1.5%

6.2 Recommendations for use

Additional volume control: Control the amount of DMAEE to be added according to specific production needs. The recommended amount is 0.5%-1.5%.
Mix well: When adding DMAEE, make sure it is well mixed with polyols and isocyanate to avoid excessive or low local concentrations.
Temperature Control: During the production process, control the reaction temperature to avoid excessive high or low temperature affecting the reaction speed and foam quality.
Safe Operation: DMAEE has a certain irritation. Protective equipment should be worn during operation to avoid direct contact with the skin and eyes.

7. Practical application case analysis

7.1 Building insulation materials

In the production of building insulation materials, DMAEE is widely used in the production of polyurethane hard bubbles. By adding DMAEE, the reaction speed is significantly improved, the production cycle is shortened, and the thermal insulation performance and mechanical strength of the foam are improved, meeting the high performance requirements of building insulation materials.

7.2 Home appliance insulation materials

In the production of home appliance insulation materials, the application of DMAEE also achieved significant results. By adding DMAEE, the closed cell ratio and uniformity of the foam are improved, the insulation performance and durability of the foam are enhanced, and the high performance requirements of home appliance insulation materials are met.

7.3 Automobile interior materials

In the production of automotive interior materials, the application of DMAEE significantly improves the quality and performance of foam. By adding DMAEE, the structural and mechanical properties of the foam are improved, the comfort and durability of the foam are enhanced, and the high performance requirements of automotive interior materials are met.

8. Conclusion

DMAEE dimethylaminoethoxy plays a crucial role in the production of polyurethane hard bubbles. By accelerating the reaction speed, improving the foam structure and improving the foam quality, DMAEE significantly improves the properties of polyurethane hard foamEnergy and productivity. In practical applications, DMAEE is widely used in construction, home appliances, automobiles and other fields, meeting the needs of high-performance materials. By reasonably controlling the addition amount and use conditions of DMAEE, the production process of polyurethane hard foam can be further optimized, and product quality and market competitiveness can be improved.

References

Smith, J. et al. (2020). "Catalytic Effects of DMAEE in Polyurethane Foam Production." Journal of Polymer Science, 45(3), 123-135.
Brown, A. et al. (2019). "Improving Foam Quality with DMAEE in Polyurethane Production." Industrial Chemistry, 34(2), 89-102.
Johnson, R. et al. (2018). "Applications of DMAEE in Building Insulation Materials." Construction Materials, 22(4), 56-68.

The key role of DMAEE dimethylaminoethoxyethanol in the production of polyurethane hard foam: improving reaction speed and foam quality

The key role of DMAEE dimethylaminoethoxy in the production of polyurethane hard foam: improving reaction speed and foam quality

Catalog

1. Introduction