Epoxy curing agent Knowledge m-chlorobenzaldehyde

m-chlorobenzaldehyde

广告位

m-chlorobenzaldehyde structural formula

Structural formula

Business number 05Z1
Molecular formula C7H5CLO
Molecular weight 140
label

3-Chlorobenzaldehyde,

3-Chlorobenzaldehyde

Numbering system

CAS number:587-04-2

MDL number:MFCD00003350

EINECS number:209-596-9

RTECS number:None

BRN number:507098

PubChem number:24854057

Physical property data

1. Physical property data

1. Properties: colorless or light yellow transparent liquid

2. Density (g/mL, 20/4℃): 1.2410

3. Refractive index (nD20): 1.5641

4. Flash point (℃): 88°C

5. Melting point: 17

6. Boiling point (ºC): 213.5

7. Refractive index at room temperature (n25): 1.561325.8

8. The liquid phase standard claims heat (enthalpy) (kJ·mol-1): -125.9

Toxicological data

None yet

Ecological data

None yet

Molecular structure data

1. Molar refractive index: 37.90

2. Molar volume (cm3/mol): 113.0

3. Isotonic specific volume (90.2K ): 288.2

4. Surface tension (dyne/cm): 42.2

5. Polarizability (10-24cm3): 15.02

Compute chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): None

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond acceptors: 1

4. Number of rotatable chemical bonds: 1

5. Number of tautomers: none

6. Topological molecule polar surface area 17.1

7. Number of heavy atoms: 9

8. Surface charge: 0

9. Complexity: 103

10. Number of isotope atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 1

Properties and stability

Chemical properties:

Properties: colorless or light yellow transparent liquid. Boiling point: Soluble in ethanol, ether, benzene and acetone, slightly soluble in water.

Storage method

Storage:

Seal the container and store it in a sealed main container in a cool, dry place.

Synthesis method

Preparation method: Obtained from m-nitrobenzaldehyde through the following steps: Cool the solution of stannous chloride and concentrated hydrochloric acid to 5°C, slowly add m-nitrobenzaldehyde in batches, stir vigorously, and the reaction process will heat up quickly. to about 100℃. Use ice salt bath to cool to about 2℃, and orange-red color will precipitate.��Crystallize to obtain a paste suspension. Add sodium nitrite aqueous solution from below the liquid surface while stirring, keeping the temperature at 0-5°C. Finally, the solution should turn the starch potassium iodide test paper blue. Add this diazonium salt solution to the cuprous chloride solution at 75°C, mix thoroughly, add concentrated hydrochloric acid, mix well, and leave overnight. Carry out steam distillation, collect the distillate, extract with diethyl ether, and dry the extract with anhydrous calcium chloride. Filter, evaporate the ether and then distill under reduced pressure. Collect the 107-109°C (3.47kPa) fraction to obtain the finished product with a yield of more than 75%.

Purpose

Usage: organic intermediate.

广告位
This article is from the Internet, does not represent the position of Epoxy curing agent, reproduced please specify the source.https://www.dmp-30.vip/archives/111393

author:

Previous article
Next article
Contact Us

Contact us

+86 - 152 2121 6908

Online consultation: QQ交谈

E-mail: info@newtopchem.com

Working hours: Monday to Friday, 9:00-17:30, closed on holidays
Follow wechat
Scan wechat and follow us

Scan wechat and follow us

Follow Weibo
Back to top
Home
Phone
Products
Search