Epoxy curing agent Knowledge Diethyl ethyl phosphate Diethyl ethylphosphonate

Diethyl ethyl phosphate Diethyl ethylphosphonate

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Ethyl diethyl phosphate structural formula

Structural formula

Business number 01MZ
Molecular formula C6H15O3P
Molecular weight 166.16
label

Diethylpropionic aldehyde,

Diethoxyethylphosphine oxide,

ethyl-phosphonic acidiethylester,

Highly efficient organophosphorus flame retardant

Numbering system

CAS number:78-38-6

MDL number:MFCD00039888

EINECS number:201-111-9

RTECS number:SZ7925000

BRN number:1756861

PubChem number:24869763

Physical property data

1. Physical property data

1. Properties: colorless and transparent liquid.

2. Density (g/mL, 25/4℃): 1.028

3. Relative vapor density (g/mL, air=1): Uncertain

4. Melting point (ºC): Uncertain

5. Boiling point (ºC, normal pressure): 200

6. Boiling point (ºC, 5.2kPa): Uncertain

7. Refractive index: 1.412~1.418 (25℃)

8. Flash point (ºC): >200

9. Specific rotation (º) : Uncertain

10. Autoignition point or ignition temperature (ºC): Uncertain

11. Vapor pressure (kPa, 25ºC): Uncertain

12. Saturated vapor pressure (kPa, 60ºC): Uncertain

13. Heat of combustion (KJ/mol): Uncertain

14. Critical temperature (ºC): Uncertain

15. Critical pressure (KPa): Uncertain

16. Log value of oil-water (octanol/water) partition coefficient: Uncertain

17. Explosion Upper limit (%, V/V): Uncertain

18. Lower explosion limit (%, V/V): Uncertain

19. Solubility: Compatible with water and organic solvents Miscible. .

Toxicological data

None yet

Ecological data

None yet

Molecular structure data

1. Molar refractive index: 40.21

2. Molar volume (cm3/mol): 164.4

3. Isotonic specific volume (90.2K): 382.3

4. Surface tension (dyne/cm): 29.2

5. Polarizability (10-24cm3): 15.94

Compute chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): 0.6

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond acceptors: 3

4. Number of rotatable chemical bonds: 5

5. Number of tautomers: none

6. Topological molecule polar surface area 35.5

7. Number of heavy atoms: 10

8. Surface charge: 0

9. Complexity: 114

10. Number of isotope atoms: 0

11. Number of determined atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of stereocenters of chemical bonds: 0

14. Uncertain number of stereocenters of chemical bonds: 0

15. Number of covalent bond units: 1

Properties and stability

None yet

Storage method

None yet

Synthesis method

Add absolute ethanol, methyl red and solvent to the reaction kettle, and evenly add the phosphorus trichloride and solvent mixture to the high tank. Pour ammonia gas into the kettle at about 0°C while stirring, and add phosphorus trichloride dropwise at the same time. Adjust the feeding speed of the two to keep the reaction temperature at 0 to 10°C. Complete the dropwise addition of phosphorus trichloride in about 2 to 3 hours. Continue to pass ammonia for a few minutes to make the reactant alkaline (pH 8 to 9). Add water to dissolve the by-product ammonium chloride and a small amount of diethyl phosphite, and let it stand to separate the water layer. The oil layer is fractionated under reduced pressure to recover the solvent. Then use vacuum fractionation to collect triethyl phosphite. The boiling point is 52~53°C (1999.8Pa). , the yield is 70% to 75%. The reaction solvent is preferably petroleum ether at about 90°C. Trichlorethylene, toluene, and xylene can also be used. Triethyl phosphite undergoes an isomerization reaction under the action of a catalyst to produce diethyl ethylphosphonate.

Purpose

This product is a new type of highly efficient organophosphorus flame retardant. It is widely added to various stearic foam plastics and has better flame retardant effect. This product has low viscosity, does not contain halogen, and is very stable in a two-component system of polyether polyol and isocyanate.

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