Epoxy curing agent Knowledge Methacrolein Methacrolein

Methacrolein Methacrolein

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Methacrolein structural formula

Structural formula

Business number 01NR
Molecular formula C4H6O
Molecular weight 70.09
label

2-Methacrolein,

methacrolein,

a-Methacrolein,

a-Methylacrolein,

Methacrylicaldehyde,

Methylacrylaldehyde

Numbering system

CAS number:78-85-3

MDL number:MFCD00006974

EINECS number:201-150-1

RTECS number:OZ2625000

BRN number:1209258

PubChem number:24848091

Physical property data

1. Properties: Colorless liquid with a strong irritating odor.

2. Density (g/mL, 25/4℃): 0.85

3. Relative density (20℃, 4℃): 0.837

4 . Melting point (ºC): -81

5. Boiling point (ºC, normal pressure): 69

6. Refractive index at room temperature(n 20D): 1.4144

7. Liquid phase standard hot melt (J·mol-1·K-1 ): 130.7

8. Flash point (ºC): -15

9. Specific rotation (º): Uncertain

10 . Autoignition point or ignition temperature (ºC): Uncertain

11. Vapor pressure (kPa, 25ºC): 16.13

12. Saturated vapor pressure (kPa, 60ºC): Uncertain Determine

13. Heat of combustion (KJ/mol): Uncertain

14. Critical temperature (ºC): Uncertain

15. Critical pressure (KPa ): Uncertain

16. Log value of oil-water (octanol/water) partition coefficient: Uncertain

17. Explosion upper limit (%, V/V): Uncertain

18. Lower explosion limit (%, V/V): Uncertain

19. Solubility: Slightly soluble in water, easily soluble in ethanol and ether.

Toxicological data

1. Acute toxicity

Rat caliber LD50: 140mg/kg; rat inhalation LC50: 125PPM/4H;

Rabbit skin LD50: 430uL/kg

2. Neurotoxicity

Rabbit skin test: 2mg/24H;

Rabbit eye test: 50ug/24H;

3. Teratogenicity

Salmonella: 500 nmol/L

Ecological data

None yet

Molecular structure data

1. Molar refractive index: 20.33

2. Molar volume (cm3/mol): 86.7

3. Isotonic specific volume (90.2K ): 185.3

4. Surface tension (dyne/cm): 20.8

5. Polarizability (10-24cm3): 8.26

Compute chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): 0.7

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond acceptors: 1

4. Number of rotatable chemical bonds: 1

5. Number of tautomers: none

6. Topological molecule polar surface area 17.1

7. Number of heavy atoms: 5

8. Surface charge: 0

9. Complexity: 54.7

10. Number of isotope atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 1

Properties and stability

1. Exist in flue-cured tobacco leaves and smoke.

Storage method

This product should be sealed and stored in a cool, dark place. Storage temperature 4ºC

Synthesis method

1. A method for preparing methacrolein, using at least one of isobutylene and tert-butyl alcohol in an oxidation catalyst composition Mo12BiaCebKcFedAeBfOg, A refers to cobalt alone, or a mixture of cobalt and magnesium with an atomic ratio of magnesium to cobalt not greater than 0.7, B refers to rubidium, cesium or their mixtures, and a, b, c, d, e, f and g are the atomic ratios of bismuth, cerium, potassium, iron, A, B and oxygen corresponding to the 12 atoms of molybdenum respectively. Through the method of the present invention, high-yield methacrolein can be stably produced by using an oxidation catalyst composition. This oxidation catalyst composition has a relatively simple combination composition and can therefore be simply prepared, and it not only has excellent The thermal stability and reduction resistance extend the catalyst life and have excellent selectivity to methacrolein, wherein the catalyst composition contains bismuth, cerium, iron and potassium in specific amounts and specific relative proportions, but does not include Those ingredients that cause environmental pollution and toxicity problems, and the preparation of raw materials does not have to use compounds with low solubility in water, such as tungsten, antimony and niobium compounds. They are usually used to obtain the required catalytic properties, but their use is due to the difficulty in obtaining homogeneous catalysts. The composition is unfavorable.

2. Tobacco: FC, 40.

Purpose

Used in the manufacture of copolymers and resins, it is the raw material for the production of methyl propionic acid and the raw material for thermoplastic monomers.

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